What is an eco-friendly alternative to silicone oils ?

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  • June 2, 2023
  • 5 minutes of read time

What is an eco-friendly alternative to silicone oils ?

Body care
Face care
Sun care
Make-up
Hair care

Silicone oils are widely used  in the cosmetic industry because of  their unique sensory benefits and properties, such as long lasting effect in lipsticks, shine and softness in hair care products ... Silicone oils are smoothing: they give products like creams or make-up a silky, spreadable and luxurious texture. 

However, their synthetic origin, lack of biodegradability, their supposed build-up effect and volatility can sometimes cause formulators to look for alternatives. 

PERHAPS YOUR MARKETING ASKS YOU TO SUBSTITUTE THEM IN YOUR FORMULAS. FIND OUT HOW IN THIS ARTICLE.

What are silicones?

The term “silicone” does not apply to a specific ingredient, but rather to a large family of ingredients. They are molecules that have alternating silicon and oxygen atoms along a carbon chain or ring—silicones were originally sourced from sand in the form of silicon dioxide. Their combination, through various chemical and synthetic processes, forms polymers with large molecular structures. Depending on the nature of the organic group and the polymerisation conditions, silicone oils can have a variety of structures and viscosities, from the most fluid, through viscous, to past or wax. Most silicones can be identified by the end of their name: “-cone, -siloxane, or -conol” are often silicone oils. 

Due to their structure, sensorial properties will be different from one silicone oil to another. Their degree of volatility determines the sensation of thickness they provide to the touch.

There are three main categories of silicones that are used in cosmetic:

  • Small silicones like cyclohexasiloxane are liquid and volatile. This gives them good delivery properties and light and evanescent touch. 
  • Silicone polymers like dimethicone are long-chain molecules and can be either liquid or solid. 
  • Functional silicones like dimethiconol, have a different structure and properties thanks to other atoms outside of the oxygen, carbon, and silicon that they contain.
cosmetic categories of silicones

Regarding the controversies often addressed to silicones such as the hair loss or congested skin they may cause, or safety issues, most silicones do not have these consequences when used under strict concentrations in a cosmetic formulation and with guidelines to follow.

But do you know that one of the main controversies  about silicone oils is their synthetic nature, the fact that they are not biodegradable(1).

What are Seppic’s alternatives to silicones?

With our EMOSMART™ & EMOGREEN™ ranges, Seppic offers a new generation of inert emollients and above all biodegradable, in line with the consumers’ demands for sustainable products and with the “clean beauty” trend becoming the new normal. The patented production process allows to obtain high purity products. These neutral alkanes (inert and non-polar) are compatible with extreme formulation conditions. They’re not sensitive to oxidation, pH change or oxidizing/reducing media. The perfect allies for formulators looking for alternatives to silicones!

EMOGREEN™ range is plant based. They are 100% natural origin content (according to ISO 16128), COSMOS and NATRUE certified.

Emosmart emogreen alternatives to silicones

Substituting silicones leads to highly sensorial emollients in the trend for beauty oils with elaborated and appealing textures that are increasingly appreciated by consumers.

The two light EMOSMART™ L15 and EMOGREEN™ L15 are evanescent, and have a shorter playtime like cyclic silicones. EMOSMART™ L19, as EMOGREEN™ L19, confers an infinite gliding to the texture and are the best alternative to low viscosity dimethicones. EMOGREEN™ L19 and EMOSMART™ C28 are defined by their touch, respectively powdery and nourishing, felt at the end of the application. These emollients can be considered as alternatives to various silicone polymers. Finally, EMOGREEN™ HP40 can replace more viscous silicones like dimethicone/dimethiconol blends and has a smooth enveloping and supple afterfeel with no tacky effect.

Performance firts!

Thanks to their chemical nature, EMOSMART™ and EMOGREEN™ are versatile oils for cosmetic products formulation. Easy-to-formulate, these fluid and clear emollients are compatible with all types of oily phases (vegetable oils, esters, silicone oils, mineral oils…) and all cosmetic applications (skin care, hair care, sun care, make-up, deodorant, make-up removal, hair color, depilatories…). They have been evaluated to be non comedogenic, matching with every skin type. 

By tribology, a rheometer with a rotary mobile, Seppic has compared  the friction coefficient of its emollients compared to some currently used silicone oils. Cyclopentasiloxane is the most raspy, rough to the touch. Low viscosity dimethicone  shows a raspy effect appearing with increasing speed. EMOSMART™ and EMOGREEN™ provide low friction & high gliding effect whatever the spreading speed. A low friction coefficient also means an easy spreading on the skin with no irritating.

Positioning these emollients as alternatives to silicone oils means offering advanced benefits in various cosmetic applications. Below are some examples of benefits Seppic has measured on EMOSMART™ & EMOGREEN™ ranges.

In hair care, EMOGREEN™ HP 40 helps to preserve keratin structure under thermal treatment in order to maintain the hair healthy and protected. Other additional performance such as anti-frizz, volume control and easy combing have been demonstrated thanks to the product’s substantivity on the hair fiber and its ability to smooth out the hair scales.

EMOGREEN™ L15 is the perfect ally to protect hair fiber from repeated mechanical stress. Tested with the Flexabrasion method, it shows its ability to reinforce the hair fiber, making it more resistant to mechanical stress (bending, friction and abrasion solicitations) over a steel wire. The results are significantly better than those obtained with cyclopentasiloxane on treated hair fibers.

In skin care, EMOGREEN™ L19 has two ways to address very dry and sensitive skin needs: on the skin, it improves the aspect, renews the sensation of comfort and in the jar it allows to formulate cosmetic products with a lower quantity of preservatives.

 

In conclusion, today's formulators have solutions to meet the expectations of their marketing and, more generally, the needs of consumers for more eco-design in cosmetic products.

EMOSMART™ and EMOGREEN™ are two ranges of easy-to-use and biodegradable emollients; they can be used in all kind of applications thanks to their versatility and sensoriality. EMOGREEN™ are the natural silicones alternative challengers.

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To remember
  1. It is possible to replace silicone oils for sustainable and responsible cosmetics
  2. EMOSMART™ and EMOGREEN™ are two ranges of high-purity alkanes, easy to use and biodegradable
  3. Today's emollients offer a wide sensory palette and properties similar or even superior to silicone oils

Sources

1 Chandra, G. (1995). A Review of the Environmental Fate and Effects of Silicone Materials in Textile Applications.

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